Generally, you can find the most user-configurable environment within Linux. AurumTech This configuration can, however, be hard to achieve. I have spent countless hours honing my Linux install to perfection. Any time that you incorporate a new software package or kernel update, you may face difficulty's. Getting graphics drivers working can be tedious, especially for high-end configurations. However, the work is worth it, if you've got the skills, to see linux working on a multi-desktop display. Another not so well known piece of software is Compiz Fusion. Compiz Fusion is Windows in it's greatest form. Your desktop is transformed into 4 desktops, all having independent window layouts, with the ability to shift between the desktops and work in individual workspaces at random.
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While Compiz operates on the plugin level, remember that it certainly can, and will cause adverse effects to your system. Be careful with Compiz settings, but if your system totally freezes, just hold the power button for 10 seconds, it will turn off, wait for 30 more, then turn it back on, boot as normal, Compiz should go with the settings that were stored before, since you didn't apply and only tested the settings. The cube setting is one of the most stunning graphical layouts for a desktop that I have ever seen, especially when spread across three monitors. The cube setting in Compiz turns the four graphical terminals provided to you by Compiz into a three dimensional cube, that you can rotate with your mouse and zoom in and out of, it also has another plug-in that makes your windows pop off of the desktop in a three-dimensional casing. Conky is a very interesting desktop 'widget' feature that allows you almost endless options as far as customization.